Until age 14, Doussopoulou attended a Greek school in England called the Hellenic College of London.
Throughout her swimming experience, she participated in the World Cup games of Glasgow, London, and Greece.
In late 1999, Doussopoulou met Turkish pop singer Mustafa Sandal with whom she performed a duet for his upcoming album Akışına Bırak.
After her success with Mustafa Sandal, Doussopoulou moved to New York for a year to record more music and demos that included a wider variety of elements and influences.
Doussopoulou ended up not signing to a label and instead flew to Los Angeles, meeting with Jimmy Iovine, the chairman of Universal Records and other music executives.
Her next album, Eisai I Mousiki Mou was released in Greece in December 2005 and in early 2006 in Turkey.