In statistical mechanics the Ornstein–Zernike (OZ) equation is an integral equation introduced[1] by Leonard Ornstein and Frits Zernike that relates different correlation functions with each other.
Together with a closure relation, it is used to compute the structure factor and thermodynamic state functions of amorphous matter like liquids or colloids.
The OZ equation has practical importance as a foundation for approximations for computing the pair correlation function of molecules or ions in liquids, or of colloidal particles.
The pair correlation function is related via Fourier transform to the static structure factor, which can be determined experimentally using X-ray diffraction or neutron diffraction.
The direct correlation function is only used in connection with the OZ equation, which can actually be seen as its definition.
[2] Besides the OZ equation, other methods for the computation of the pair correlation function include the virial expansion at low densities, and the Bogoliubov–Born–Green–Kirkwood–Yvon (BBGKY) hierarchy.
Any of these methods must be combined with a physical approximation: truncation in the case of the virial expansion, a closure relation for OZ or BBGKY.
It can be written where the first equality comes from homogeneity, the second from isotropy, and the equivalences introduce new notation.
It is convenient to define the total correlation function as: which expresses the influence of molecule 1 on molecule 2 at distance
splits this influence into two contributions, a direct and indirect one.
This indirect effect is weighted by the density and averaged over all the possible positions of molecule 3.
[3] The integral in the OZ equation is a convolution.
Therefore, the OZ equation can be resolved by Fourier transform.
, respectively, and use the convolution theorem, we obtain which yields As both functions,
, are unknown, one needs an additional equation, known as a closure relation.
While the OZ equation is purely formal, the closure must introduce some physically motivated approximation.
In the low-density limit, the pair correlation function is given by the Boltzmann factor, with
The best known closure approximations are:[5][6] The latter two interpolate in different ways between the former two, and thereby achieve a satisfactory description of particles that have a hard core and attractive forces.