Paint mixing

Mixing pigments for the purpose of creating realistic paintings with diverse color gamuts is known to have been practiced at least since Ancient Greece.

The identity of a/the set of minimal pigments to mix diverse gamuts has long been the subject of speculation by theorists whose claims have changed over time, for example Pliny's white, black, one or another red, and "sil", which might have been yellow or blue; Robert Boyle's white, black, red, yellow, and blue; and variations with more or fewer "primary" color or pigments.

[2]: 29–38  Nonetheless, it has long been known that limited palettes consisting of a small set of pigments are sufficient to mix a diverse gamut of colors.

[13] The set of pigments available to mix diverse gamuts of color (in various media such as oil, watercolor, acrylic, gouache, and pastel) is large and has changed throughout history.

Color predictions that incorporate light scattering effects of pigment particles and paint layer thickness require approaches based on the Kubelka–Munk[19] equations.

Even such approaches cannot predict the color of paint mixtures precisely since small variances in particle size distribution, impurity concentrations etc.

There are hundreds of commercially available pigments for visual artists to use and mix (in various media such as oil, watercolor, acrylic, gouache, and pastel).

A common approach is to use just a limited palette of primary pigments[21] (often between four and eight) that can be physically mixed to any color that the artist desires in the final work.

A self-portrait by Anders Zorn clearly showing a four pigment palette of what are thought to be white, yellow ochre , red vermilion and black pigments. [ 1 ]
Three oil paints, one of which is mixed with wax
A set of watercolors