Potassium hexafluorophosphate is a chemical compound with the formula KPF6.
This colourless salt consists of potassium cations and hexafluorophosphate anions.
It is prepared from phosphorus pentachloride:[2] This exothermic reaction is conducted in liquid hydrogen fluoride.
The salt is stable in a hot alkaline aqueous solution, from which it can be recrystallized.
These salts are often less soluble than the closely related tetrafluoroborates.