A second major barrier came with QFT's apparent inability to describe the weak and strong interactions, to the point where some theorists called for the abandonment of the field theoretic approach.
[2]: 19 Despite the enormous success of classical electromagnetism, it was unable to account for the discrete lines in atomic spectra, nor for the distribution of blackbody radiation in different wavelengths.
He treated atoms, which absorb and emit electromagnetic radiation, as tiny oscillators with the crucial property that their energies can only take on a series of discrete, rather than continuous, values.
In 1924, Louis de Broglie proposed the hypothesis of wave–particle duality, that microscopic particles exhibit both wave-like and particle-like properties under different circumstances.
Observationally, the Schrödinger equation underlying quantum mechanics could explain the stimulated emission of radiation from atoms, where an electron emits a new photon under the action of an external electromagnetic field, but it was unable to explain spontaneous emission, where an electron spontaneously decreases in energy and emits a photon even without the action of an external electromagnetic field.
Theoretically, the Schrödinger equation could not describe photons and was inconsistent with the principles of special relativity—it treats time as an ordinary number while promoting spatial coordinates to linear operators.
It was between 1928 and 1930 that Jordan, Eugene Wigner, Heisenberg, Pauli, and Enrico Fermi discovered that material particles could also be seen as excited states of quantum fields.
[6] Faced with these infinities, John Archibald Wheeler and Heisenberg proposed, in 1937 and 1943 respectively, to supplant the problematic QFT with the so-called S-matrix theory.
By ignoring the contribution of photons whose energy exceeds the electron mass, Hans Bethe successfully estimated the numerical value of the Lamb shift.
The breakthrough eventually came around 1950 when a more robust method for eliminating infinities was developed by Julian Schwinger, Richard Feynman, Freeman Dyson, and Shinichiro Tomonaga.
[8]: 2 Given the tremendous success of QED, many theorists believed, in the few years after 1949, that QFT could soon provide an understanding of all microscopic phenomena, not only the interactions between photons, electrons, and positrons.
[13] Motivated by the former findings, Schwinger kept pursuing this approach in order to "quantumly" generalize the classical process of coupling external forces to the configuration space parameters known as Lagrange multipliers.
[22] Harald Fritzsch, Murray Gell-Mann, and Heinrich Leutwyler discovered in 1971 that certain phenomena involving the strong interaction could also be explained by non-Abelian gauge theory.
[8]: 3 The Higgs boson, central to the mechanism of spontaneous symmetry breaking, was finally detected in 2012 at CERN, marking the complete verification of the existence of all constituents of the Standard Model.
The first supersymmetric QFT in four dimensions was built by Yuri Golfand and Evgeny Likhtman in 1970, but their result failed to garner widespread interest due to the Iron Curtain.
Supersymmetry theories only took off in the theoretical community after the work of Julius Wess and Bruno Zumino in 1973,[8]: 7 but to date have not been widely accepted as part of the Standard Model due to lack of experimental evidence.
Historically, the Higgs mechanism of spontaneous symmetry breaking was a result of Yoichiro Nambu's application of superconductor theory to elementary particles, while the concept of renormalization came out of the study of second-order phase transitions in matter.
In the case of the real scalar field, the existence of these operators was a consequence of the decomposition of solutions of the classical equations of motion into a sum of normal modes.
The path integral formulation of QFT is concerned with the direct computation of the scattering amplitude of a certain interaction process, rather than the establishment of operators and state spaces.
[1]: 82 The free two-point function, also known as the Feynman propagator, can be found for the real scalar field by either canonical quantization or path integrals to be[1]: 31,288 [32]: 23 In an interacting theory, where the Lagrangian or Hamiltonian contains terms
In canonical quantization, the two-point correlation function can be written as:[1]: 87 where ε is an infinitesimal number and ϕI is the field operator under the free theory.
[1]: 98 In realistic applications, the scattering amplitude of a certain interaction or the decay rate of a particle can be computed from the S-matrix, which itself can be found using the Feynman diagram method.
[1]: 798 [32]: 421 The renormalization group, developed by Kenneth Wilson, is a mathematical apparatus used to study the changes in physical parameters (coefficients in the Lagrangian) as the system is viewed at different scales.
[1]: 410–411 As an example, the coupling constant in QED, namely the elementary charge e, has the following β function: where Λ is the energy scale under which the measurement of e is performed.
[1]: 420 The coupling constant g in quantum chromodynamics, a non-Abelian gauge theory based on the symmetry group SU(3), has the following β function: where Nf is the number of quark flavours.
For example, the cut-off could be the inverse of the atomic spacing in a condensed matter system, and in elementary particle physics it could be associated with the fundamental "graininess" of spacetime caused by quantum fluctuations in gravity.
The remaining two degrees of freedom are said to be "redundant" — apparently different ways of writing Aμ can be related to each other by a gauge transformation and in fact describe the same state of the photon field.
[1]: 797 [32]: 443 The ϕ4 theory, QED, QCD, as well as the whole Standard Model all assume a (3+1)-dimensional Minkowski space (3 spatial and 1 time dimensions) as the background on which the quantum fields are defined.
For a special class of QFTs called topological quantum field theories (TQFTs), all correlation functions are independent of continuous changes in the spacetime metric.
[57] Since the 1950s,[58] theoretical physicists and mathematicians have attempted to organize all QFTs into a set of axioms, in order to establish the existence of concrete models of relativistic QFT in a mathematically rigorous way and to study their properties.