[1][2][3] Native α-allophycocyanin requires an exogenous protein, known as a lyase, to attach the chromophore, phycocyanobilin.
[6] The extinction coefficient (180,000 M−1 cm−1) of smURFP is extremely large and has a modest quantum yield (0.18), which makes it comparable biophysical brightness to eGFP and ~2-fold brighter than most red or far-red fluorescent proteins derived from coral.
smURFP nanoparticles of ~10-14 nm diameter can be synthesized in an oil and water emulsion and remain fluorescent.
[13] Free smURFP, purified protein and not genetically encoded, can be encapsulated into viruses and used for non-invasive, fluorescence imaging of biodistribution in living mice.
Researchers showed purified smURFP has a limit of detection of 0.4 nM for biliverdin in human serum.
[18] Tandem dimer smURFP (TDsmURFP) was used as an exogenous fluorescent marker to label the seven-transmembrane receptor Smoothened (SMO).
TDsmURFP was purified from E. coli and attached to SMO by sortase-mediated conjugation for fluorescence-activated cell sorting (FACS).
The smURFP-tag accepts a biliverdin substrate modified on a carboxylate with a polyethylene glycol (PEG) linker to the cargo molecule.
Unlike the Halo-, SNAP-, and CLIP-tags that use the substrate to only covalently attach the cargo molecule, biliverdin is fluorogenic, and fluorescence is turned "on" with covalent attachment to the smURFP-tag to allow far-red fluorescence tracking of cargo molecule in living cells.
Biliverdin modification on a single carboxylate creates a neutral molecule that passes the outer and nuclear membrane of mammalian cells.
[21] Despite showing comparable biophysical brightness to eGFP when purified protein was normalized, this was not seen in living cells.
Add 1-5 μM biliverdin dimethyl ester in media or buffer containing 10% fetal bovine serum (FBS).
A rationally designed red fluorescent protein, stagRFP, allows for easier creation of FRET sensors.
The new sensor allowed for simultaneous visualization of three kinases, Src, Akt, ERK, in a single cell.
Note, these fusions are fragments that contain a nuclear localization signal and ubiquitination sites for degradation, but are not functional proteins.