Tetra-amido macrocyclic ligand

Tetra-amido macrocyclic ligands (TAMLs) constitute a class of macrocyclic ligands.

When complexed to metals, TAMLs are proposed as environmentally friendly catalysts.

Although never commercialized, iron-TAML complexes catalyze the degradation of pesticides, effluent streams from paper mills, dibenzothiophenes from diesel fuels, and anthrax spores.

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Structure of an Fe-TAML complex.