Ultrafast electron diffraction

The diffraction signal is, subsequently, detected by an electron counting instrument such as a charge-coupled device camera.

Ultrafast electron diffraction can provide a wealth of dynamics on charge carriers, atoms, and molecules.

Generating high-flux ultrashort electron beams has been relatively straightforward, but pulse duration below a picosecond proved extremely difficult due to space-charge effects.

Radio-frequency (RF) compression has emerged has an leading method of reducing the pulse expansion in ultrafast electron diffraction experiments, achieving temporal resolution well below 50 femtoseconds.

[6] Shorter electron beams below 10 femtoseconds are ultimately required to probe the fastest dynamics in solid state materials and observe gas phase molecular reactions.

[8] When studying reversible process, especially weak signals caused by, e.g., thermal diffuse scattering, a diffraction pattern is accumulated from many electron bunches, as many as

[10] High reciprocal space resolution allows for the detection of Bragg diffraction spots that correspond to long periodicity phenomena.

Temporal resolution is primarily a function of the bunch length of the electrons and the relative timing jitters between the pump and probe.

Schematic of Ultrafast Electron Diffraction showing the pump pulse (red) exciting the sample prior to the arrival of the electron probe pulse (blue)