She was a contract artist of GMA Network and moved to ABS-CBN in August 2013.

She is known for her roles in the GMA network's shows like the telefantasya Mga Mata ni Anghelita, Who's Your Daddy Now?

She is the daughter of actress Nadia Montenegro and former Caloocan Mayor, Macario "Boy" Asistio, Jr.[2] and the niece of Hazel Ann Mendoza.

Asistio has dated high-profile Philippine actors such as Mark Herras and Derek Ramsay.

[9] In July 2022, she married Bully Carbonel, and welcomed their child Ava Zafina.