[1][2] She was the fifth child of Countess Izabela Czartoryska née Fleming and her husband Prince Adam Kazimierz Czartoryski, though her father may actually have been Count Franciszek Ksawery Branicki.

[1] She ran a salon in Warsaw for Enlightenment era reform leaders of Poland-Lithuania.

Czartoryska was regarded by her contemporaries as a great beauty and sat for numerous portraits.

[1][2] She is nicknamed "the mother of the Zamyoski house", as she gave birth to ten children: Konstanty (born in 1799), Andrzej Artur (1800), Jan (1802), Władysław (1803), Celina (1804), Jadwiga (1806), Zdzisław (1810), August (1811), Eliza (1818) and Stanisław (1820).

She was buried at Santa Croce, her funerary monument was created by sculptor Lorenzo Bartolini.