Abietic acid

Chemically, it is a complicated molecule featuring two alkene groups and a carboxylic acid within a chiral tricyclic framework.

Through the process of diagenesis, abietic acid changes into a collection of simpler compounds called abietanes.

In air and in the presence of certain cytochrome P450 enzymes, abietadiene is oxidized to abietic acid.

The stereochemistry of the typical abietane skeleton suggests a GGPP precursor with its fused cyclohexyl rings in a chair-chair ("normal") conformation, although some abietanes with alternative stereochemistry may be cyclized from CCP isomers containing alternative combinations of boat and chair cyclohexane conformers.

Laboratory procedures illustrate the nature of the extraction, which is the basis of a substantial industry, formerly known as naval stores.

NFPA 704 four-colored diamond Health 1: Exposure would cause irritation but only minor residual injury. E.g. turpentine Flammability 0: Will not burn. E.g. water Instability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogen Special hazards (white): no code
Route from copalyl pyrophosphate to abietadiene , precursor to abietic acid (PP = pyrophosphate).
Abietenes are synthesized from geranylgeranyl diphosphate via a copalyl diphosphate intermediate by class 2 diterpene cyclases and class 1 diterpene syntheses. [ 5 ]