Aluminium carbide has an unusual crystal structure that consists of alternating layers of Al2C and Al2C2.
[5] Similar reactions occur with other protic reagents:[1] Reactive hot isostatic pressing (hipping) at ≈40 MPa of the appropriate mixtures of Ti, Al4C3 graphite, for 15 hours at 1300 °C yields predominantly single-phase samples of Ti2AlC0.5N0.5, 30 hours at 1300 °C yields predominantly single-phase samples of Ti2AlC (Titanium aluminium carbide).
[3] An alternative reaction begins with alumina, but it is less favorable because of generation of carbon monoxide.
[9] An aluminium-aluminium carbide composite material can be made by mechanical alloying, by mixing aluminium powder with graphite particles.
[citation needed] Aluminium carbide particles finely dispersed in aluminium matrix lower the tendency of the material to creep, especially in combination with silicon carbide particles.