Positively charged electrons (Positrons) are emitted from the nucleus as it undergoes β+ decay.
The positron travels a short distance (a few millimeters), depositing any excess energy before it combines with a free electron.
Annihilation radiation is not monoenergetic, unlike gamma rays produced by radioactive decay.
The production mechanism of annihilation radiation introduces Doppler broadening.
[2] The annihilation peak produced in a photon spectrum by annihilation radiation therefore has a higher full width at half maximum (FWHM) than decay-generated gamma rays in spectrum.