Boron differs from the other group members in its hardness, refractivity and reluctance to participate in metallic bonding.
[5] Although situated in p-block, the group is notorious for violation of the octet rule by its members boron and (to a lesser extent) aluminium.
Chlorine also forms stable compounds with all of the elements in the boron group, including thallium, and is hypothesized to react with nihonium.
Iodine will react with all natural elements in the periodic table except for the noble gases, and is notable for its explosive reaction with aluminium to form AlI3.
[17] Tennessine, the sixth and final member of group 17, may also form compounds with the elements in the boron group; however, because Tennessine is purely synthetic and thus must be created artificially, its chemistry has not been investigated, and any compounds would likely decay nearly instantly after formation due to its extreme radioactivity.
Conversely, all elements with atomic numbers are less than or equal to 66 (except Tc, Pm, Sm and Eu) have at least one isotope that is theoretically energetically stable to all forms of decay (with the exception of proton decay, which has never been observed, and spontaneous fission, which is theoretically possible for elements with atomic numbers greater than 40).
Many improvements followed, a significant advance being made just two years later by Friedrich Wöhler, whose slightly modified procedure still yielded an impure product.
The first pure sample of aluminium is credited to Henri Etienne Sainte-Claire Deville, who substituted sodium for potassium in the procedure.
[27][28] The method used today, electrolysis of aluminium oxide dissolved in cryolite, was developed by Charles Martin Hall and Paul Héroult in the late 1880s.
[27] Thallium, the heaviest stable element in the boron group, was discovered by William Crookes and Claude-Auguste Lamy in 1861.
In 1863 Ferdinand Reich and his assistant, Hieronymous Theodor Richter, were looking in a sample of the mineral zinc blende, also known as sphalerite (ZnS), for the spectroscopic lines of the newly discovered element thallium.
While examining the spectroscopic lines in zinc blende the French chemist Paul Emile Lecoq de Boisbaudran found indications of a new element in the ore.
In just three months he was able to produce a sample, which he purified by dissolving it in a potassium hydroxide (KOH) solution and sending an electric current through it.
[38] Thallium, like indium, is named after the Greek word for the color of its spectroscopic line: thallos, meaning a green twig or shoot.
It is known to occur in over a hundred different minerals and ores, however: the main source is borax, but it is also found in colemanite, boracite, kernite, tusionite, berborite and fluoborite.
[42] Major world miners and extractors of boron include Turkey, the United States, Argentina, China, Bolivia and Peru.
Aluminium is now known to occur in nearly as many minerals as boron, including garnets, turquoises and beryls, but the main source is the ore bauxite.
The world's leading countries in the extraction of aluminium are Ghana, Suriname, Russia and Indonesia, followed by Australia, Guinea and Brazil.
Gallium can be found as a trace in a variety of ores, including bauxite and sphalerite, and in such minerals as diaspore and germanite.
[45] The gallium content is greater in a few minerals, including gallite (CuGaS2), but these are too rare to be counted as major sources and make negligible contributions to the world's supply.
As is the case for most other elements found in ores and minerals, the indium extraction process has become more efficient in recent years, ultimately leading to larger yields.
In minerals it is found in moderate quantities: some examples are crookesite (in which it was first discovered), lorandite, routhierite, bukovite, hutchinsonite and sabatierite.
With the exception of synthetic nihonium, all the elements in the boron group have numerous uses and applications in the production and content of many items.
It is most often encountered in construction materials, in electrical devices, especially as the conductor in cables, and in tools and vessels for cooking and preserving food.
Gallium arsenide has been used in semiconductors, in amplifiers, in solar cells (for example in satellites) and in tunnel diodes for FM transmitter circuits.
[51] Among the items in which indium may be found are platings, bearings, display devices, heat reflectors, phosphors, and nuclear control rods.
Boron's chemistry does allow it to form complexes with such important molecules as carbohydrates, so it is plausible that it could be of greater use in the human body than previously thought.
[57] The symptoms of boron toxicity are numerous in plants, complicating research: they include reduced cell division, decreased shoot and root growth, decreased production of leaf chlorophyll, inhibition of photosynthesis, lowering of stomata conductance,[58] reduced proton extrusion from roots,[59] and deposition of lignin and suberin.
Its most noticeable effect, apparent even from tiny doses, is hair loss all over the body, but it causes a wide range of other symptoms, disrupting and eventually halting the functions of many organs.
Due to its strong radioactivity, it would definitely be extremely toxic, although significant quantities of nihonium (larger than a few atoms) have not yet been assembled.