Carbon dioxide

In the air, carbon dioxide is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas.

Plants, algae and cyanobacteria use energy from sunlight to synthesize carbohydrates from carbon dioxide and water in a process called photosynthesis, which produces oxygen as a waste product.

Other commercial applications include food and beverage production, metal fabrication, cooling, fire suppression and stimulating plant growth in greenhouses.

[20] In the gas phase, carbon dioxide molecules undergo significant vibrational motions and do not keep a fixed structure.

Only very strong nucleophiles, like the carbanions provided by Grignard reagents and organolithium compounds react with CO2 to give carboxylates: In metal carbon dioxide complexes, CO2 serves as a ligand, which can facilitate the conversion of CO2 to other chemicals.

[26] Photoautotrophs (i.e. plants and cyanobacteria) use the energy contained in sunlight to photosynthesize simple sugars from CO2 absorbed from the air and water: Carbon dioxide is colorless.

[28] This form of glass, called carbonia, is produced by supercooling heated CO2 at extreme pressures (40–48 GPa, or about 400,000 atmospheres) in a diamond anvil.

[31] Phototrophs use the products of their photosynthesis as internal food sources and as raw material for the biosynthesis of more complex organic molecules, such as polysaccharides, nucleic acids, and proteins.

[32] A globally significant species of coccolithophore is Emiliania huxleyi whose calcite scales have formed the basis of many sedimentary rocks such as limestone, where what was previously atmospheric carbon can remain fixed for geological timescales.Plants can grow as much as 50% faster in concentrations of 1,000 ppm CO2 when compared with ambient conditions, though this assumes no change in climate and no limitation on other nutrients.

Additionally, and crucially to life on earth, photosynthesis by phytoplankton consumes dissolved CO2 in the upper ocean and thereby promotes the absorption of CO2 from the atmosphere.

[47] Concentrations of 7% to 10% (70,000 to 100,000 ppm) may cause suffocation, even in the presence of sufficient oxygen, manifesting as dizziness, headache, visual and hearing dysfunction, and unconsciousness within a few minutes to an hour.

[54] At this CO2 concentration, International Space Station crew experienced headaches, lethargy, mental slowness, emotional irritation, and sleep disruption.

[53] However a review of the literature found that a reliable subset of studies on the phenomenon of carbon dioxide induced cognitive impairment to only show a small effect on high-level decision making (for concentrations below 5000 ppm).

Miners, who are particularly vulnerable to gas exposure due to insufficient ventilation, referred to mixtures of carbon dioxide and nitrogen as "blackdamp", "choke damp" or "stythe".

Before more effective technologies were developed, miners would frequently monitor for dangerous levels of blackdamp and other gases in mine shafts by bringing a caged canary with them as they worked.

[67] CO2 is the parameter that changes the fastest (with hygrometry and oxygen levels when humans or animals are gathered in a closed or poorly ventilated room).

It is also why flight attendants instruct passengers, in case of loss of cabin pressure, to apply the oxygen mask to themselves first before helping others; otherwise, one risks losing consciousness.

As an example, the chemical reaction between methane and oxygen: Iron is reduced from its oxides with coke in a blast furnace, producing pig iron and carbon dioxide:[104] Carbon dioxide is a byproduct of the industrial production of hydrogen by steam reforming and the water gas shift reaction in ammonia production.

[105] It is produced by thermal decomposition of limestone, CaCO3 by heating (calcining) at about 850 °C (1,560 °F), in the manufacture of quicklime (calcium oxide, CaO), a compound that has many industrial uses: Acids liberate CO2 from most metal carbonates.

[18]: 3  Other commercial applications include food and beverage production, metal fabrication, cooling, fire suppression and stimulating plant growth in greenhouses.

With the exception of British real ale, draught beer is usually transferred from kegs in a cold room or cellar to dispensing taps on the bar using pressurized carbon dioxide, sometimes mixed with nitrogen.

Aluminium capsules of CO2 are also sold as supplies of compressed gas for air guns, paintball markers/guns, inflating bicycle tires, and for making carbonated water.

[132] Carbon dioxide has also been widely used as an extinguishing agent in fixed fire-protection systems for local application of specific hazards and total flooding of a protected space.

[133] International Maritime Organization standards recognize carbon dioxide systems for fire protection of ship holds and engine rooms.

[135] Carbon dioxide has attracted attention in the pharmaceutical and other chemical processing industries as a less toxic alternative to more traditional solvents such as organochlorides.

Due to the need to operate at pressures of up to 130 bars (1,900 psi; 13,000 kPa), CO2 systems require highly mechanically resistant reservoirs and components that have already been developed for mass production in many sectors.

Its environmental advantages (GWP of 1, non-ozone depleting, non-toxic, non-flammable) could make it the future working fluid to replace current HFCs in cars, supermarkets, and heat pump water heaters, among others.

Methods to administer CO2 include placing animals directly into a closed, prefilled chamber containing CO2, or exposure to a gradually increasing concentration of CO2.

The American Veterinary Medical Association's 2020 guidelines for carbon dioxide induction state that a displacement rate of 30–70% of the chamber or cage volume per minute is optimal for the humane euthanasia of small rodents.

His interpretation was that the rest of the charcoal had been transmuted into an invisible substance he termed a "gas" (from Greek "chaos") or "wild spirit" (spiritus sylvestris).

Structural formula of carbon dioxide with bond length
Structural formula of carbon dioxide with bond length
Ball-and-stick model of carbon dioxide
Ball-and-stick model of carbon dioxide
Space-filling model of carbon dioxide
Space-filling model of carbon dioxide
NFPA 704 four-colored diamond Health 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroform Flammability 0: Will not burn. E.g. water Instability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogen Special hazard SA: Simple asphyxiant gas. E.g. nitrogen, helium
Stretching and bending oscillations of the CO 2 molecule. Upper left: symmetric stretching. Upper right: antisymmetric stretching. Lower line: degenerate pair of bending modes.
Electrical conductivity of carbondioxide saturated desalinated water when heated from 20 to 98 °C. The shadowed regions indicate the error bars associated with the measurements. Data on github . A comparison with the temperature dependence of vented desalinated water can be found here .
Pellets of "dry ice", a common form of solid carbon dioxide
Pressure–temperature phase diagram of carbon dioxide. Note that it is a log-lin chart.
Overview of the Calvin cycle and carbon fixation
Overview of photosynthesis and respiration. Carbon dioxide (at right), together with water, form oxygen and organic compounds (at left) by photosynthesis (green), which can be respired (red) to water and CO 2 .
Symptoms of carbon dioxide toxicity, by increasing volume percent in air [ 45 ]
Rising levels of CO 2 threatened the Apollo 13 astronauts, who had to adapt cartridges from the command module to supply the carbon dioxide scrubber in the Apollo Lunar Module , which they used as a lifeboat.
A carbon dioxide sensor that measures CO 2 concentration using a nondispersive infrared sensor
Atmospheric CO 2 concentration measured at Mauna Loa Observatory in Hawaii from 1958 to 2023 (also called the Keeling Curve ). The rise in CO 2 over that time period is clearly visible. The concentration is expressed as μmole per mole, or ppm .
Annual CO 2 flows from anthropogenic sources (left) into Earth's atmosphere, land, and ocean sinks (right) since the 1960s. Units in equivalent gigatonnes carbon per year. [ 89 ]
Pterapod shell dissolved in seawater adjusted to an ocean chemistry projected for the year 2100
Pie chart of commercial CO2 use. See caption for description.
The biggest commercial uses of CO2 are in producing urea for fertilizer and in extracting oil from the ground. Beverages, food, metal fabrication, and other uses account for 3%, 3%, 2%, and 4% of commercial CO2 use, respectively. [ 106 ]
Carbon dioxide bubbles in a soft drink
Dry ice used to preserve grapes after harvest
Use of a CO 2 fire extinguisher
Comparison of the pressure–temperature phase diagrams of carbon dioxide (red) and water (blue) as a log-lin chart with phase transitions points at 1 atmosphere
Crystal structure of dry ice