Copper

Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement.

[10] Commonly encountered compounds are copper(II) salts, which often impart blue or green colors to such minerals as azurite, malachite, and turquoise, and have been used widely and historically as pigments.

Copper is essential to all living organisms as a trace dietary mineral because it is a key constituent of the respiratory enzyme complex cytochrome c oxidase.

[13] Copper, silver, and gold are in group 11 of the periodic table; these three metals have one s-orbital electron on top of a filled d-electron shell and are characterized by high ductility, and electrical and thermal conductivity.

[14] At the macroscopic scale, introduction of extended defects to the crystal lattice, such as grain boundaries, hinders flow of the material under applied stress, thereby increasing its hardness.

This is due to the low plasma frequency of the metal, which lies in the red part of the visible spectrum, causing it to absorb the higher-frequency green and blue colors.

According to the British Geological Survey, in 2005, Chile was the top producer of copper with at least one-third of the world share followed by the United States, Indonesia and Peru.

[32] The amount of copper in use is increasing and the quantity available is barely sufficient to allow all countries to reach developed world levels of usage.

[33] An alternative source of copper for collection currently being researched are polymetallic nodules, which are located at the depths of the Pacific Ocean approximately 3000–6500 meters below sea level.

[52] Greenhouse gas emissions primarily arise from electricity consumed by the company, especially when sourced from fossil fuels, and from engines required for copper extraction and refinement.

Copper is one of the most important constituents of silver and karat gold solders used in the jewelry industry, modifying the color, hardness and melting point of the resulting alloys.

[60] The alloy of 90% copper and 10% nickel, remarkable for its resistance to corrosion, is used for various objects exposed to seawater, though it is vulnerable to the sulfides sometimes found in polluted harbors and estuaries.

[28] Shakudō is a Japanese decorative alloy of copper containing a low percentage of gold, typically 4–10%, that can be patinated to a dark blue or black color.

Specifically, using Benedict's reagent and Fehling's solution the presence of the sugar is signaled by a color change from blue Cu(II) to reddish copper(I) oxide.

[104] Natural bronze, a type of copper made from ores rich in silicon, arsenic, and (rarely) tin, came into general use in the Balkans around 5500 BC.

The rich copper deposits of Cornwall seem to have been largely untouched, in spite of extensive tin mining in the region, for reasons likely social and political rather than technological.

[121] The German scientist Gottfried Osann invented powder metallurgy in 1830 while determining the metal's atomic mass; around then it was discovered that the amount and type of alloying element (e.g., tin) to copper would affect bell tones.

Introduction of open pit steam shovel mining and innovations in smelting, refining, flotation concentration and other processing steps led to mass production.

[123] Flash smelting was developed by Outokumpu in Finland and first applied at Harjavalta in 1949; the energy-efficient process accounts for 50% of the world's primary copper production.

[133] Many electrical devices rely on copper wiring because of its multitude of inherent beneficial properties, such as its high electrical conductivity, tensile strength, ductility, creep (deformation) resistance, corrosion resistance, low thermal expansion, high thermal conductivity, ease of soldering, malleability, and ease of installation.

[141][142] The rapid growth of these sources in the 21st century has been prompted by increasing costs of fossil fuels as well as their environmental impact issues that significantly lowered their use.

When planning for a new renewable power facility, engineers and product specifiers seek to avoid supply shortages of selected materials.

[155][156][157][158] Roofs, flashings, rain gutters, downspouts, domes, spires, vaults, and doors have been made from copper for hundreds or thousands of years.

Copper's architectural use has been expanded in modern times to include interior and exterior wall cladding, building expansion joints, radio frequency shielding, and antimicrobial and decorative indoor products such as attractive handrails, bathroom fixtures, and counter tops.

Some of copper's other important benefits as an architectural material include low thermal movement, light weight, lightning protection, and recyclability.

In addition, the EPA has approved a long list of antimicrobial copper products made from these alloys, such as bedrails, handrails, over-bed tables, sinks, faucets, door knobs, toilet hardware, computer keyboards, health club equipment, and shopping cart handles.

[184] Copper may be used as a speculative investment due to the predicted increase in use from worldwide infrastructure growth, and the important role it has in producing wind turbines, solar panels, and other renewable energy sources.

[206][207] The U.S. Institute of Medicine (IOM) updated the estimated average requirements (EARs) and recommended dietary allowances (RDAs) for copper in 2001.

[220][221] In the US, the Occupational Safety and Health Administration (OSHA) has designated a permissible exposure limit (PEL) for copper dust and fumes in the workplace as a time-weighted average (TWA) of 1 mg/m3.

[222] The National Institute for Occupational Safety and Health (NIOSH) has set a recommended exposure limit (REL) of 1 mg/m3, time-weighted average.

Color lines in a spectral range
A copper disc (99.95% pure) made by continuous casting ; etched to reveal crystallites
Copper just above its melting point keeps its pink luster color when enough light outshines the orange incandescence color.
Unoxidized copper wire (left) and oxidized copper wire (right)
The East Tower of the Royal Observatory, Edinburgh , showing the contrast between the refurbished copper installed in 2010 and the green color of the original 1894 copper
Native copper from the Keweenaw Peninsula, Michigan, about 2.5 inches (6.4 cm) long
Chuquicamata , in Chile, is one of the world's largest open pit copper mines .
World production trend
Price of Copper 1959–2022
Scheme of flash smelting process
Copper alloys are widely used in the production of coinage; seen here are two examples – post-1964 American dimes , which are composed of the alloy cupronickel [ 55 ] and a pre-1968 Canadian dime , which is composed of an alloy of 80 percent silver and 20 percent copper. [ 56 ]
A sample of copper(I) oxide
Copper(II) gives a deep blue coloration in the presence of ammonia ligands. The one used here is tetraamminecopper(II) sulfate .
Pourbaix diagram for copper in uncomplexed media (anions other than OH- not considered). Ion concentration 0.001 m (mol/kg water). Temperature 25 °C.
Ball-and-stick model of the complex [Cu(NH 3 ) 4 (H 2 O) 2 ] 2+ , illustrating the octahedral coordination geometry common for copper(II)
A corroded copper ingot from Zakros , Crete , shaped in the form of an animal skin ( oxhide ) typical in that era
Many tools during the Chalcolithic Era included copper, such as the blade of this replica of Ötzi 's axe.
Copper ore ( chrysocolla ) in Cambrian sandstone from Chalcolithic mines in the Timna Valley , southern Israel
Copper artifacts from the Old Copper Complex of North America, which may have existed from approximately 9500–5400 years before present
Copper was used in blue pigments like this " Egyptian Blue " faience saucer and stand from the Bronze Age, New Kingdom of Egypt (1400–1325 BC).
In alchemy the symbol for copper was also the symbol for the goddess and planet Venus .
Chalcolithic copper mine in Timna Valley , Negev Desert , Israel
Mississippian copper plates from North America were produced in this style from around 800–1600 AD.
Acid mine drainage affecting the stream running from the disused Parys Mountain copper mines
18th-century copper kettle from Norway made from Swedish copper
Chalcography of the city of Vyborg at the turn of the 17th and 18th centuries. The year 1709 carved on the printing plate.
Copper fittings for soldered plumbing joints
A very large copper seal end cap
Copper electrical busbars distributing power to a large building
Copper wires for recycling
Copper roof on the Minneapolis City Hall , coated with patina
Old copper utensils in a Jerusalem restaurant
Large copper bowl. Dhankar Gompa .
Rich sources of copper include oysters, beef and lamb liver, Brazil nuts, blackstrap molasses, cocoa, and black pepper. Good sources include lobster, nuts and sunflower seeds, green olives, avocados, and wheat bran.
Photosynthesis functions by an elaborate electron transport chain within the thylakoid membrane . A central link in this chain is plastocyanin , a blue copper protein.