Since she was a child, Pérez Volpin dreamed of studying medicine, influenced by her father who was a director of the Juan A. Fernández Hospital in the city of Buenos Aires.

She, like all of the group that had entered, began in production and was under the orders of Ricardo Pipino whose function was to form the new channel that was going to be released, Todo Noticias.

As a host -when she did not do it alone- she worked with José Antonio Gil Vidal, Mario Mazzone, Juan Micelli, Guillermo Lobo, Luis Otero, Santo Biasatti and Marcelo Bonelli.

On 25 April 2005 the morning news program Arriba Argentinos began, and Pérez Volpin was chosen as a host along with Juan Miceli.

[3] In 2017, she entered politics and was elected legislator of the City of Buenos Aires as part of the Evolución front led by Martín Lousteau.

On Monday, 5 February 2018, she entered the Trinidad Sanatorium of the city of Buenos Aires, which determined she had a "complex abdominal condition.

[5][6] The journalist's family went to court and presented a complaint to dispute the claims of the sanatorium and on 7 February Judge Gabriel Ghirlanda determined Pérez Volpin's was a "wrongful homicide".

[7] After conducting an autopsy in the judicial morgue her remains were veiled in the Buenos Aires legislature on 8 February with public access between 2 and 10 pm, which was attended by four thousand people.

[11] On 19 June 2018, endoscopist Diego Bioalolenkier and anesthesiologist Nélida Inés Puente were indicted, the only two individuals charged in the case.