He married Martha Marín, and the couple had two sons, Eduardo and Carlos, and a daughter, María Marta.
In 1953 Angeloz received his first Radical Civic Union Party mandate as President of the Youth Board in the city of Córdoba.
Angeloz was the UCR presidential candidate in the 1989 elections, but was defeated by Justicialist Party nominee Carlos Menem.
Shortly before being sworn in he was charged with embezzlement, together with some relatives and close friends who had served in high public positions during his mandate.
He died after complications from a hip-break fall combined with an undisclosed pre-existing condition on 23 August 2017.