Hexanitrohexaazaisowurtzitane

[1] While most development of CL-20 has been fielded by the Thiokol Corporation, the US Navy (through ONR) has also been interested in CL-20 for use in rocket propellants, such as for missiles, as it has lower observability characteristics such as less visible smoke.

[5] First, benzylamine (1) is condensed with glyoxal (2) under acidic and dehydrating conditions to yield the first intermediate compound.(3).

[6] In August 2011, Adam Matzger and Onas Bolton published results showing that a cocrystal of CL-20 and TNT had twice the stability of CL-20—safe enough to transport, but when heated to 136 °C (277 °F) the cocrystal may separate into liquid TNT and a crystal form of CL-20 with structural defects that is somewhat less stable than CL-20.

It is confirmed that the increase of the effective sizes and dimensionality of the CL-20 covalent systems leads to their thermodynamic stability growth.

Numerical calculations of CL-20 chains and networks' electronic characteristics revealed that they were wide-bandgap semiconductors.

Partially condensed, stereo, skeletal formula of hexanitrohexaazaisowurtzitane
Partially condensed, stereo, skeletal formula of hexanitrohexaazaisowurtzitane
Ball and stick model of hexazaisowurtzitane
Ball and stick model of hexazaisowurtzitane
Synthesis of CL20