Rapolano Terme is a comune (municipality) in the Province of Siena in the Italian region Tuscany, located about 60 kilometres (37 mi) southeast of Florence and about 20 kilometres (12 mi) east of Siena in the area known as the Crete Senesi.

Until 1949 it was known simply as Rapolano.

The municipality includes several minor towns, among which the village of Serre di Rapolano.

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