[17] Arrhenius's "ytterbite" reached Johan Gadolin, a Royal Academy of Turku professor, and his analysis yielded an unknown oxide ("earth" in the geological parlance of the day[17]), which he called yttria.
Further spectroscopic analysis between 1886 and 1901 of samaria, yttria, and samarskite by William Crookes, Lecoq de Boisbaudran and Eugène-Anatole Demarçay yielded several new spectral lines that indicated the existence of an unknown element.
The Russian chemist R. Harmann proposed that a new element he called "ilmenium" should be present in this mineral, but later, Christian Wilhelm Blomstrand, Galissard de Marignac, and Heinrich Rose found only tantalum and niobium (columbium) in it.
Due to their chemical similarity, the concentrations of rare earths in rocks are only slowly changed by geochemical processes, making their proportions useful for geochronology and dating fossils.
[34] The high field strength[clarification needed] and large ionic radii of rare earths make them incompatible with the crystal lattices of most rock-forming minerals, so REE will undergo strong partitioning into a melt phase if one is present.
[36] Well-known minerals containing yttrium, and other HREE, include gadolinite, xenotime, samarskite, euxenite, fergusonite, yttrotantalite, yttrotungstite, yttrofluorite (a variety of fluorite), thalenite, and yttrialite.
[36] Well-known minerals containing cerium, and other LREE, include bastnäsite, monazite, allanite, loparite, ancylite, parisite, lanthanite, chevkinite, cerite, stillwellite, britholite, fluocerite, and cerianite.
Monazite (marine sands from Brazil, India, or Australia; rock from South Africa), bastnäsite (from Mountain Pass rare earth mine, or several localities in China), and loparite (Kola Peninsula, Russia) have been the principal ores of cerium and the light lanthanides.
[36] Enriched deposits of rare-earth elements at the surface of the Earth, carbonatites and pegmatites, are related to alkaline plutonism, an uncommon kind of magmatism that occurs in tectonic settings where there is rifting or that are near subduction zones.
[34][35] Large carbonatite deposits enriched in rare-earth elements include Mount Weld in Australia, Thor Lake in Canada, Zandkopsdrift in South Africa, and Mountain Pass in the USA.
In tropical regions where precipitation is high, weathering forms a thick argillized regolith, this process is called supergene enrichment and produces laterite deposits; heavy rare-earth elements are incorporated into the residual clay by absorption.
One square patch of metal-rich mud 2.3 kilometers wide might contain enough rare earths to meet most of the global demand for a year, Japanese geologists report in Nature Geoscience."
Consequentially, REE are characterized by a substantial identity in their chemical reactivity, which results in a serial behaviour during geochemical processes rather than being characteristic of a single element of the series.
[43][45] The Browns Range mine, located 160 km south east of Halls Creek in northern Western Australia, was under development in 2018 and is positioned to become the first significant dysprosium producer outside of China.
[68][70] As of March 2022[update], 2,700 mining collection pools scattered across 300 separate locations were found in Kachin State, encompassing the area of Singapore, and an exponential increase from 2016.
[53][73] Significant sites under development outside China include Steenkampskraal in South Africa, the world's highest grade rare earths and thorium mine, closed in 1963, but has been gearing to go back into production.
[43][82] A second large deposit of REEs at Elk Creek in southeast Nebraska[83] is under consideration by NioCorp Development Ltd [84] who hopes to open a niobium, scandium, and titanium mine there.
[94] Many Danish politicians have expressed concerns that other nations, including China, could gain influence in thinly populated Greenland, given the number of foreign workers and investment that could come from Chinese companies in the near future because of the law passed December 2012.
[96] Adding to potential mine sites, ASX listed Peak Resources announced in February 2012, that their Tanzanian-based Ngualla project contained not only the 6th largest deposit by tonnage outside of China but also the highest grade of rare-earth elements of the 6.
[106] In early 2011, Australian mining company Lynas was reported to be "hurrying to finish" a US$230 million rare-earth refinery on the eastern coast of Peninsular Malaysia's industrial port of Kuantan.
[107] The Kuantan development brought renewed attention to the Malaysian town of Bukit Merah in Perak, where a rare-earth mine operated by a Mitsubishi Chemical subsidiary, Asian Rare Earth, closed in 1994 and left continuing environmental and health concerns.
[124] In France, the Rhodia group is setting up two factories, in La Rochelle and Saint-Fons, that will produce 200 tons of rare earths a year from used fluorescent lamps, magnets, and batteries.
This campaign is expected to be concentrated in the South,[142] where mines – commonly small, rural, and illegal operations – are particularly prone to releasing toxic waste into the general water supply.
[162] The rare-earth mining and smelting process can release airborne fluoride which will associate with total suspended particles (TSP) to form aerosols that can enter human respiratory systems.
[144] According to The Economist, "Slashing their exports of rare-earth metals ... is all about moving Chinese manufacturers up the supply chain, so they can sell valuable finished goods to the world rather than lowly raw materials.
It was reported,[179] but officially denied,[180] that China instituted an export ban on shipments of rare-earth oxides (but not alloys) to Japan on 22 September 2010, in response to the detainment of a Chinese fishing boat captain by the Japanese Coast Guard.
[181][60] On September 2, 2010, a few days before the fishing boat incident, The Economist reported that "China ... in July announced the latest in a series of annual export reductions, this time by 40% to precisely 30,258 tonnes.
Since 2009 the USGS has conducted remote sensing surveys as well as fieldwork to verify Soviet claims that volcanic rocks containing rare-earth metals exist in Helmand Province near the village of Khanashin.
The USGS study team has located a sizable area of rocks in the center of an extinct volcano containing light rare-earth elements including cerium and neodymium.
Due to its role in permanent magnets used for wind turbines, it has been argued that neodymium will be one of the main objects of geopolitical competition in a world running on renewable energy.