ScBr3 is produced through the burning of scandium in bromine gas.
[4] Scandium bromide can also be prepared by reacting excess hydrobromic acid with scandium oxide, and the hexahydrate can be crystallized from the solution.
[5] The anhydrous form can be produced by the reaction of bromine, scandium oxide and graphite in nitrogen gas.
[7] Scandium bromide is used for solid state synthesis of unusual clusters such as Sc19Br28Z4, (Z=Mn, Fe, Os or Ru).
These clusters are of interest for their structure and magnetic properties.