[2][3] Three Ukrainian archers qualified for the women's events by virtue of the nation's podium finish in the team recurve competition at the 2016 Archery World Cup meet in Antalya, Turkey.

Artem Pochtarev and Marija Ulitina were selected among the top 34 individual shuttlers each in the men's and women's singles based on the BWF World Rankings as of 5 May 2016.

With the top seed Nicola Adams of Great Britain advancing to the semifinals at the World Championships, Tetyana Kob earned an Olympic spot as a result of her third-place finish at the 2016 European Qualification Tournament in Samsun, Turkey.

[8] On June 16, 2016, Dmytro Mytrofanov received a spare Olympic berth as the next highest-ranked boxer, not yet qualified, in the middleweight division of the AIBA Pro Boxing Rankings, after Turkey's Adem Kılıççı was suspended for failing the re-tested doping sample on steroids from London 2012.

[10][11] Ukraine qualified one canoeist in the women's K-1 class by obtaining a top finish at the 2016 European Canoe Slalom Championships in Liptovský Mikuláš, Slovakia.

[17] Ukraine fielded a squad of four jumping riders into the Olympic equestrian competition by virtue of a top national finish from Central & Eastern Europe at the FEI qualification event in Šamorín, Slovakia.

[19] Meanwhile, sabre fencer Andriy Yahodka claimed his Olympic spot by finishing among the top four individuals at the European Zonal Qualifier in Prague, Czech Republic.

The full Ukrainian fencing team, led by London 2012 épée champion Yana Shemyakina and sabre bronze medalist Olha Kharlan, was named on July 5, 2016.

[24] Ukraine qualified one gymnast in the women's trampoline by virtue of a top six finish at the 2016 Olympic Test Event in Rio de Janeiro.

Eight rowers (four per gender) were selected to the Ukrainian roster for the Games, with Anastasiya Kozhenkova looking to defend the Olympic title with the women's quadruple sculls crew (Buryak, Nimchenko, & Verkhogliad).

Margaryta Pesotska was originally granted an invitation from ITTF to compete in the same event as one of the next seven highest-ranked eligible players, not yet qualified, on the Olympic Ranking List, but later withdrew from the Games due to injury.

[41][42] Ukrainian weightlifters qualified four men's and four women's quota places for the Rio Olympics based on their combined team standing by points at the 2014 and 2015 IWF World Championships.

[44][45] Three further wrestlers claimed the remaining Olympic slots to round out the Ukrainian roster at the final meet of the World Qualification Tournament in Istanbul.