Among them were Greco-Roman wrestler Davor Štefanek, the first Serbian to win an Olympic gold in the sport after 32 years; long jumper Ivana Španović, the nation's first track and field athlete to stand on the Olympic podium in six decades; taekwondo fighter Tijana Bogdanović, who captured a silver in the women's flyweight category (49 kg); and kayak tandem Marko Tomićević and Milenko Zorić, who were runners-up in the long-distance double (men's K-2 1000 m).

It was the nation's second-largest delegation sent to the Olympics, falling short of the record for the most number of athletes (116) achieved in London four years earlier by nearly 12 percent.

Highlighting the list of Serbian athletes were Beijing 2008 bronze medalist Novak Djokovic, who entered the Games as the world's top-ranked tennis player in the men's singles, and taekwondo fighter Milica Mandić, who became the country's first ever Olympic champion in London four years earlier.

Rifle shooting legend Stevan Pletikosić, who officially made his sixth Olympic appearance, topped the nation's roster lineup as the oldest and most experienced competitor (aged 43).

Meanwhile, Pletikosic's female counterpart Ivana Anđušić Maksimović, who followed her father Goran's sporting legacy to win a silver medal in the small-bore rifle at London 2012, acted as the flag bearer for the Serbian team in the opening ceremony.

[1] Other notable athletes on the Serbian roster included long jumper and European outdoor champion Ivana Španović, pistol shooters Zorana Arunović (European Games gold medalist) and Andrea Arsović (European champion and world's top-ranked), freestyle swimmer and London 2012 finalist Velimir Stjepanović, water polo team captain Živko Gocić, and basketballers Miloš Teodosić (team captain and EuroLeague champion), Nikola Jokić (who currently played for NBA's Denver Nuggets) and Ana Dabović (WNBA's Los Angeles Sparks and EuroBasket MVP).

[16] The entire shooting squad was named to the Serbian roster for the Games on 6 July 2016, with rifle specialist Stevan Pletikosić becoming the first male shooter to compete at his sixth Olympics.

Notable absence in the roster was pistol legend Jasna Šekarić, who bid to establish a historic milestone as one of the first female athletes, alongside Georgian shooter Nino Salukvadze to appear in eight editions of the Games.

Aleksandar Karakašević granted an invitation from ITTF to compete in the men's singles as one of the next seven highest-ranked eligible players, not yet qualified, on the Olympic Ranking List.

Having been directly entered to the singles, Djokovic and Janković also opted to play with their partners Nenad Zimonjić and Aleksandra Krunić, respectively, in the men's and women's doubles.

Key: The Serbian men's water polo team qualified for the Olympics by winning the 2015 FINA World League Super Final in Italy.