Differences in O2 solubility and measured concentration (AOU) typically occur when biological activity, ocean circulation, or ocean mixing act to change the ambient concentration of oxygen.
In shallow water systems (e.g. lakes), the full water column is generally in close contact with the atmosphere, and oxygen concentrations are typically close to saturation, and AOU values are near zero.
In deep water systems (e.g. oceans), water can be out of contact with the atmosphere for extremely long periods of time (years, decades, centuries) and large positive AOU values are typical.
On occasion, where near-surface primary production has raised oxygen concentrations above saturation, negative AOU values are possible (i.e. oxygen has not been utilized to below saturation concentrations).
[3] Increased AOU is likely also contributing to declining ocean O2 concentrations.