Nitroxyl

Hydrogen oxonitrate(I) Hyponitrous acid monomer Nitronous oxide Nitroxyl (common name) or azanone (IUPAC name)[2] is the chemical compound HNO.

The conjugate base, NO−, nitroxide anion, is the reduced form of nitric oxide (NO) and is isoelectronic with dioxygen.

Nitroxyl is a weak acid, with pKa of about 11, the conjugate base being the triplet state of NO−, sometimes called nitroxide.

[10][11] Nitroxyl rapidly decomposes by a bimolecular pathway to nitrous oxide (k at 298 K = 8×106 M s):[10] The reaction proceeds via dimerization to hyponitrous acid, H2N2O2, which subsequently undergoes dehydration.

[12] Nitroxyl donors, known as nitroso compounds, show potential in the treatment of heart failure and ongoing research is focused on finding new molecules for this task.

Ball and stick model of nitroxyl
Ball and stick model of nitroxyl
Nitrosocyclohexyl acetate
Nitrosocyclohexyl acetate