Oxonickelates

Fine tuning of properties is achievable with mixtures of elements, applying stress or pressure, or varying the physical form.

These include the chloronickelates, fluoronickelates, tetrabromonickelates, tetraiodonickelates, cyanonickelates, nitronickelates and other nickel-organic acid complexes such as oxalatonickelates.

Other rare-earth nickelates can function as fuel cell catalysts.

The ability to switch between an insulating and a conducting state in some of these materials is of interest in the development of new transistors, that have higher on to off current ratios.

[2] The rare-earth nickelates were first made by Demazeau et al. in 1971, by heating a mixture of oxides under high pressure oxygen, or potassium perchlorate.