Comonomer

In polymer chemistry, a comonomer refers to a polymerizable precursor to a copolymer aside from the principal monomer.

The distribution of comonomers is referred to as the "blockiness" of a copolymer.

The advantages to such copolymers has led to a focus on catalysts that facilitate the incorporation of these comonomers, e.g., constrained geometry complexes.

[1] Comonomers are often employed to improve the plastification of polymeric materials, i.e. the flexibility of the polymer.

Copolymers however have many applications/ They are produced by copolymerization of alkyl acrylates and one or more of the following comonomers methyl methacrylate, styrene, acrylonitrile, vinyl acetate, vinyl chloride, vinylidene chloride, and butadiene.

In this conversion, 1-hexene (red) is a comonomer in the formation of a modified polyethylene.