It is an oil, possessing an odor similar to that of brown sugar.
At its boiling point of 171.9 °C, it converts into crotonic acid.
The compound can be prepared from 1,3‑dibromo-2‑butanone via the Favorskii rearrangement.
[2] Ethyl isocrotonate can be prepared by semihydrogenation of ethyl tetrolate.
[3] Rudolph Fittig and Hugo Erdmann showed that the γ-phenyl structural analog of isocrotonic acid forms α-naphthol when dehydrated, an observation that provided useful evidence in understanding the nature of naphthalene.