Liquid hydrogen

[5] A common method of obtaining liquid hydrogen involves a compressor resembling a jet engine in both appearance and principle.

The first synthesis of the stable isomer form of liquid hydrogen, parahydrogen, was achieved by Paul Harteck and Karl Friedrich Bonhoeffer in 1929.

It slowly undergoes an exothermic reaction to become the para isomer, with enough energy released as heat to cause some of the liquid to boil.

[8] To prevent loss of the liquid during long-term storage, it is therefore intentionally converted to the para isomer as part of the production process, typically using a catalyst such as iron(III) oxide, activated carbon, platinized asbestos, rare earth metals, uranium compounds, chromium(III) oxide, or some nickel compounds.

Due to its similarity, builders can sometimes modify and share equipment with systems designed for liquefied natural gas (LNG).

Since neutrons and hydrogen nuclei have similar masses, kinetic energy exchange per interaction is maximum (elastic collision).

However, the high combustion temperatures and present atmospheric nitrogen can result in the breaking of N≡N bonds, forming toxic NOx if no exhaust scrubbing is done.

Even with thermally insulated containers it is difficult to keep such a low temperature, and the hydrogen will gradually leak away (typically at a rate of 1% per day[12]).

It also shares many of the same safety issues as other forms of hydrogen, as well as being cold enough to liquefy, or even solidify atmospheric oxygen, which can be an explosion hazard.

Hydrogen itself is biologically inert and its only human health hazard as a vapor is displacement of oxygen, resulting in asphyxiation, and its very high flammability and ability to detonate when mixed with air.

NFPA 704 four-colored diamond Health 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gas Flammability 4: Will rapidly or completely vaporize at normal atmospheric pressure and temperature, or is readily dispersed in air and will burn readily. Flash point below 23 °C (73 °F). E.g. propane Instability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogen Special hazard CRYO: Cryogenic
Liquid hydrogen bubbles forming in two glass flasks at the Bevatron laboratory in 1955
A large hydrogen tank in a vacuum chamber at the Glenn Research Center in Brook Park, Ohio , in 1967
A Linde AG tank for liquid hydrogen at the Museum Autovision in Altlußheim , Germany, in 2008
Two U.S. Department of Transportation placards indicating the presence of hazardous materials , which are used with liquid hydrogen