Nitroso

[9] Organonitroso compounds serve as a ligands giving transition metal nitroso complexes.

[11] Nitrosyls are non-organic compounds containing the NO group, for example directly bound to the metal via the N atom, giving a metal–NO moiety.

Their presence in finished products has been tightly regulated since several food-poisoning cases in the early 20th century,[12] but consumption of large quantities of processed meats can still cause a slight elevation in gastric and oesophageal cancer risk today.

[13][14][15][16] For example, during the 1970s, certain Norwegian farm animals began exhibiting elevated levels of liver cancer.

[18][19] Stomach acid catalyzes nitrosamine compound formation and is the main location of the reaction during digestion.

[20] The formation process is inhibited when amine concentration is low (e.g. a low-protein diet or no fermented food).

[22][23][24] However, when 10% of the meal is fat, the effect reverses, and ascorbic acid markedly increases nitrosamine formation.

[20][25] Vitamin C and erythorbic acid are already commonly used in the meat industry because they enhance the binding of nitrite to myoglobin, encouraging the formation of the desired pink color.

Structural formula of nitroso group
Structure of 2-nitrosotoluene dimer [ 3 ]
Linear and bent metal nitrosyls