Sublimation sandwich method

In this method, the environment around a single crystal or a polycrystalline plate is filled with vapor heated to between 1600°C and 2100°C.

Parameters that can affect crystal growth include source-to-substrate distance, temperature gradient, and the presence of tantalum for gathering excess carbon.

High growth rates are the result of small source-to-seed distances combined with a large heat flux onto a small amount of source material with no more than a moderate temperature difference between the substrate and the source (0.5-10°C).

The growth of large boules, however, remains quite difficult using this method, and it is better suited to the creation of epitaxial films with uniform polytype structures.

[1] Ultimately, samples with a thickness of up to 500 μm can be produced using this method.

Si is silicon , C is carbon , SiC 2 is silicon dicarbide , Si 2 C is disilicon carbide , Ar is gaseous argon