Condensed matter physicists seek to understand the behavior of these phases by experiments to measure various material properties, and by applying the physical laws of quantum mechanics, electromagnetism, statistical mechanics, and other physics theories to develop mathematical models and predict the properties of extremely large groups of atoms.
[5] The field overlaps with chemistry, materials science, engineering and nanotechnology, and relates closely to atomic physics and biophysics.
[7] According to the founding director of the Max Planck Institute for Solid State Research, physics professor Manuel Cardona, it was Albert Einstein who created the modern field of condensed matter physics starting with his seminal 1905 article on the photoelectric effect and photoluminescence which opened the fields of photoelectron spectroscopy and photoluminescence spectroscopy, and later his 1907 article on the specific heat of solids which introduced, for the first time, the effect of lattice vibrations on the thermodynamic properties of crystals, in particular the specific heat.
Davy observed that of the forty chemical elements known at the time, twenty-six had metallic properties such as lustre, ductility and high electrical and thermal conductivity.
[16] Shortly after, in 1869, Irish chemist Thomas Andrews studied the phase transition from a liquid to a gas and coined the term critical point to describe the condition where a gas and a liquid were indistinguishable as phases,[19] and Dutch physicist Johannes van der Waals supplied the theoretical framework which allowed the prediction of critical behavior based on measurements at much higher temperatures.
[27] Band structure calculations were first used in 1930 to predict the properties of new materials, and in 1947 John Bardeen, Walter Brattain and William Shockley developed the first semiconductor-based transistor, heralding a revolution in electronics.
[28] This phenomenon, arising due to the nature of charge carriers in the conductor, came to be termed the Hall effect, but it was not properly explained at the time because the electron was not experimentally discovered until 18 years later.
It also implied that the Hall conductance is proportional to a topological invariant, called Chern number, whose relevance for the band structure of solids was formulated by David J. Thouless and collaborators.
[40][41]: 69, 74 Shortly after, in 1982, Horst Störmer and Daniel Tsui observed the fractional quantum Hall effect where the conductance was now a rational multiple of the constant
[48] A satisfactory theoretical description of high-temperature superconductors is still not known and the field of strongly correlated materials continues to be an active research topic.
In 2012, several groups released preprints which suggest that samarium hexaboride has the properties of a topological insulator[49] in accord with the earlier theoretical predictions.
Modern theoretical studies involve the use of numerical computation of electronic structure and mathematical tools to understand phenomena such as high-temperature superconductivity, topological phases, and gauge symmetries.
Theoretical understanding of condensed matter physics is closely related to the notion of emergence, wherein complex assemblies of particles behave in ways dramatically different from their individual constituents.
[37][43] For example, a range of phenomena related to high temperature superconductivity are understood poorly, although the microscopic physics of individual electrons and lattices is well known.
[51] Similarly, models of condensed matter systems have been studied where collective excitations behave like photons and electrons, thereby describing electromagnetism as an emergent phenomenon.
[22]: 90–91 This classical model was then improved by Arnold Sommerfeld who incorporated the Fermi–Dirac statistics of electrons and was able to explain the anomalous behavior of the specific heat of metals in the Wiedemann–Franz law.
[55] Calculating electronic properties of metals by solving the many-body wavefunction is often computationally hard, and hence, approximation methods are needed to obtain meaningful predictions.
[53]: 330–337 Finally in 1964–65, Walter Kohn, Pierre Hohenberg and Lu Jeu Sham proposed the density functional theory (DFT) which gave realistic descriptions for bulk and surface properties of metals.
Understanding the behavior of quantum phase transition is important in the difficult tasks of explaining the properties of rare-earth magnetic insulators, high-temperature superconductors, and other substances.
However, it can only roughly explain continuous phase transition for ferroelectrics and type I superconductors which involves long range microscopic interactions.
Several condensed matter experiments involve scattering of an experimental probe, such as X-ray, optical photons, neutrons, etc., on constituents of a material.
Visible light has energy on the scale of 1 electron volt (eV) and is used as a scattering probe to measure variations in material properties such as the dielectric constant and refractive index.
X-rays have energies of the order of 10 keV and hence are able to probe atomic length scales, and are used to measure variations in electron charge density and crystal structure.
[61] : 258–259 In experimental condensed matter physics, external magnetic fields act as thermodynamic variables that control the state, phase transitions and properties of material systems.
[68]: 69 [69]: 185 Quantum oscillations is another experimental method where high magnetic fields are used to study material properties such as the geometry of the Fermi surface.
Common experimental methods include NMR, nuclear quadrupole resonance (NQR), implanted radioactive probes as in the case of muon spin spectroscopy (
The method involves using optical lasers to form an interference pattern, which acts as a lattice, in which ions or atoms can be placed at very low temperatures.
[71] In particular, they are used to engineer one-, two- and three-dimensional lattices for a Hubbard model with pre-specified parameters, and to study phase transitions for antiferromagnetic and spin liquid ordering.
[74] Research in condensed matter physics[43][75] has given rise to several device applications, such as the development of the semiconductor transistor,[6] laser technology,[61] magnetic storage, liquid crystals, optical fibres[76] and several phenomena studied in the context of nanotechnology.
[78] Such molecular machines were developed for example by Nobel laureates in chemistry Ben Feringa, Jean-Pierre Sauvage and Fraser Stoddart.