It is bounded by the Department of Science and Technology Complex to the southwest, Camp Bagong Diwa, Upper Bicutan Elementary School and Division of Taguig City and Pateros to the southeast, and the Justice Hall-DPWH Compound to the northeast.

Upper Bicutan National High School was introduced by Congressman Allan Peter Cayetano through House bill no.

The first seven months was the most difficult time in the history of the academe with no equipment and materials for teaching; students patiently sat on rice sacks just to learn and teachers alternately rest and work in one table with two chairs and one electric fan.

Equipment and materials were gradually raised through partnership with the non-governmental organization like the Philippine Business for Social Progress (PBSP), Mead Johnson, GIL@S to name a few.

In July, 2010, there had been a major reshuffling of principals in the Division of Taguig City and Pateros, which appointed Mrs. Guia R. Dela Cruz to the position.