[1] Cementite nanowires have been observed in Damascus steel, a material dating back to c. 900 AD, their origin and means of manufacture also unknown.
[2] Although nanoparticles are associated with modern science, they were used by artisans as far back as the ninth century in Mesopotamia for creating a glittering effect on the surface of pots.
These nanoparticles are created by the artisans by adding copper and silver salts and oxides together with vinegar, ochre, and clay on the surface of previously glazed pottery.
Toumey's analysis also includes comments from distinguished scientists in nanotechnology who say that “Plenty of Room” did not influence their early work, and in fact most of them had not read it until a later date.
Feynman's stature as a Nobel laureate and as an iconic figure in 20th century science surely helped advocates of nanotechnology and provided a valuable intellectual link to the past.
[11] Japanese scientist Norio Taniguchi of Tokyo University of Science was the first to use the term "nano-technology" in a 1974 conference,[12] to describe semiconductor processes such as thin film deposition and ion beam milling exhibiting characteristic control on the order of a nanometer.
[13][14][15] In the 1980s the idea of nanotechnology as a deterministic, rather than stochastic, handling of individual atoms and molecules was conceptually explored in depth by K. Eric Drexler, who promoted the technological significance of nano-scale phenomena and devices through speeches and two influential books.
He also first published the term "grey goo" to describe what might happen if a hypothetical self-replicating machine, capable of independent operation, were constructed and released.
Nanotechnology and nanoscience got a boost in the early 1980s with two major developments: the birth of cluster science and the invention of the scanning tunneling microscope (STM).
The scanning tunneling microscope, an instrument for imaging surfaces at the atomic level, was developed in 1981 by Gerd Binnig and Heinrich Rohrer at IBM Zurich Research Laboratory, for which they were awarded the Nobel Prize in Physics in 1986.
In the 1920s, Irving Langmuir, winner of the 1932 Nobel Prize in Chemistry, and Katharine B. Blodgett introduced the concept of a monolayer, a layer of material one molecule thick.
Smalley's research in physical chemistry investigated formation of inorganic and semiconductor clusters using pulsed molecular beams and time of flight mass spectrometry.
In the early 1990s, a team of researchers from the Max Planck Institute for Nuclear Physics and University of Arizona discovered how to synthesize and purify large quantities of fullerenes.
[42][43][44] Thomas Ebbesen and Pulickel Ajayen demonstrated a method to produce carbon nanotubes at scales allowing their properties to be measured in a laboratory.
[47][48] A 2024 review stated that over 5,000 tons of nanotubes were produced annually, with industrial applications including biosensors, satellite sensors, and marine coatings.
[49][50][51][52] Practical challenges in many applications remain, such as the difficulty of retaining their unique properties in composite materials, ensuring chemical stability, and potential for toxicity.
“The NNI serves as the central point of communication, cooperation, and collaboration for all Federal agencies engaged in nanotechnology research, bringing together the expertise needed to advance this broad and complex field.
In a 21 January 2000 speech[58] at the California Institute of Technology, Clinton said, "Some of our research goals may take twenty or more years to achieve, but that is precisely why there is an important role for the federal government."
On December 3, 2003, Bush signed into law the 21st Century Nanotechnology Research and Development Act,[60] which authorizes expenditures for five of the participating agencies totaling US$3.63 billion over four years.
[62] "Why the future doesn't need us" is an article written by Bill Joy, then Chief Scientist at Sun Microsystems, in the April 2000 issue of Wired magazine.
In the article, he argues that "Our most powerful 21st-century technologies — robotics, genetic engineering, and nanotech — are threatening to make humans an endangered species."
He argues that 20th-century technologies of destruction, such as the nuclear bomb, were limited to large governments, due to the complexity and cost of such devices, as well as the difficulty in acquiring the required materials.
[67] Smalley criticized Drexler's work on nanotechnology as naive, arguing that chemistry is extremely complicated, reactions are hard to control, and that a universal assembler is science fiction.
Smalley also believed that Drexler's speculations about apocalyptic dangers of self-replicating machines that have been equated with "molecular assemblers" would threaten the public support for development of nanotechnology.
The report contains an annex (appendix) on grey goo, which cites a weaker variation of Richard Smalley's contested argument against molecular manufacturing.
It concludes that there is no evidence that autonomous, self replicating nanomachines will be developed in the foreseeable future, and suggests that regulators should be more concerned with issues of nanoparticle toxicology.