Furanose

The name derives from its similarity to the oxygen heterocycle furan, but the furanose ring does not have double bonds.

The highest numbered chiral carbon (typically to the left of the oxygen in a Haworth projection) determines whether or not the structure has a d-configuration or L-configuration.

In an l-configuration furanose, the substituent on the highest numbered chiral carbon is pointed downwards out of the plane, and in a D-configuration furanose, the highest numbered chiral carbon is facing upwards.

The furanose ring will have either alpha or beta configuration, depending on which direction the anomeric hydroxy group is pointing.

Typically, the anomeric carbon undergoes mutarotation in solution, and the result is an equilibrium mixture of α and β configurations.